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Official Journal of the Asia Oceania Geosciences Society (AOGS)

Table 2 Brief summary of various analytical methods for detecting various As species in different samples

From: Arsenic through aquatic trophic levels: effects, transformations and biomagnification—a concise review

Sample type/matrix

Species of arsenic

Sample pre-treatment (if any)

Separation and detection method

Blood

As(III), As(V), MMA, DMA, AB

Centrifugation/ dilution (HgCl2) followed by ultrafiltration

LC-ICP-MS

Animal urine/ excreta

Dilution with deionized water and filtration

IC-ICP-MS

HPLC-ICPMS

HPLC-HG-ICPMS

Fish and oyster tissues

Lyophilization/microwave digestion

CE-ICP-MS

Fish

Ultrasonic extraction and 4 different experimental conditions

HG-AFS

Water

As(III), As(V)

Dilution with deionized water and filtration

ICP-MS

HPLC-ICPMS

HPLC-HG-ICPMS

Groundwater

Sediment and fly ash

Total As

Extraction with HNO3, acetic acid, EDTA

HG-AAS

Soil

  1. LC liquid chromatography, ICP-MS inductively couple mass spectrometry, IC ion chromatography, HPLC high-pressure liquid chromatography, CE capillary electrophoresis, HG-AFS hydride generation atomic fluorescence, HG-AAS hydride generation atomic absorption spectroscopy